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SVHC测试
欧盟ECHA12月7日发布第二批15中SVHC清单确定
浏览数:11169  发布时间:2021-10-26

2009年12月7日欧盟ECHA于发布公告,确定将15种新的SVHC增加到候选清单中,准备在2010年1月正式列入候选清单。

下面是15种新的SVHC增加到候选清单:

序号

物质名称

EC

CAS

提议理由

可能用途

测试

1

蒽油

292-602-7

90640-80-5

VPVB
C 2

主要用于制造其他物质,如提炼蒽、碳黑,也用于炸药的还原促进剂,以及海洋捕捞、防腐。

GC-MS测试蒽;
或用蒸馏方法测试5种物质

2

蒽油、蒽糊、轻油

295-278-5

91995-17-4

VPVB
CM 2

3

蒽油、蒽糊、蒽馏分

295-275-9

91995-15-2

VPVB
CM 2

4

蒽油、少蒽

292-604-8

90640-82-7

VPVB
CM 2

5

蒽油、蒽糊

292-603-2

90640-81-6

VPVB
CM 2

6

高温煤沥青

266-028-2

65996-93-2

VPVB
C 2

主要用于制作工业电极,少量用于重度防腐、铺路、黏土制作

蒸馏法

7

丙烯酰胺

201-173-7

79-06-1

CM2

主要用于聚合成聚丙烯酰胺(PAM),用于废水处理、造纸工业

GC-MS

8

硅酸铝耐火陶瓷纤维(CLP 1272/2008索引 650-017-00-8)
: Al2O3 43.5 – 47 %
和 SiO2: 49.5 – 53.5 % w/w,或
Al2O3: 45.5 – 50.5 %
w/w, 和SiO2: 48.5 – 54 % w/w,
纤维直径小于6 μm

 

 

C2

工业绝缘隔热材料

高含量时,FT-IR;
低含量时,ICP-OES测试特征离子铝、硅

9

锆硅酸铝耐火陶瓷纤维(CLP 1272/2008索引 650-017-00-8)
Al2O3: 35 – 36 % w/w,
• SiO2: 47.5 – 50 % w/w,
• ZrO2: 15 - 17 % w/w,
纤维直径小于6 μm

 

 

C2

工业绝缘隔热材料

高含量时,FT-IR;
低含量时,ICP-OES测试特征离子铝、硅、锆

10

2,4-二硝基甲苯

204-450-0

121-14-2

C2

用于制作甲苯二异氰酸盐(酯)(TDI),进而制造聚亚胺酯泡沫;也用于制造白明胶塑料。

GC-MS

11

邻苯二甲酸二异丁酯(DIBP)

201-553-2

84-69-5

R2

增塑剂

GC-MS

12

铬酸铅

231-846-0

7758-97-6

CR2

色素,用于塑料、油漆着色

测试特征离子铬(或六价铬)、铅、钼,ICP-OES

13

钼铬酸铅红(CI颜料红104)

235-759-9

12656-85-8

CR2

14

铬酸铅黄(CI颜料黄34)

215-693-7

1344-37-2

CR2

15

三(2-氯乙基)磷酸盐(TCEP)

204-118-5

115-96-8

R2

阻燃剂

GC-MS

注释:

C2- Carcinogen, category 2,M2- Mutagen, category 2 ,R2- Toxic for reproduction,category 2,表示致癌、致基因突变、致生殖毒素的2类物质,即CMR2;
VPVB- Persistent, bioaccumULative and toxic; Very persistent and very bioaccumULative;,表示高积累、高持久的生物毒性物质;
CI-colour index,颜色指数

企业应对:
新的15种SVHC在2010年1月列入候选清单后,与第一批15种SVHC一同构成30种SVHC,当30种SVHC中的任何一种:
1、作为物质提供给下游客户时,必须说明该物质;
2、在混合物(配制品)中浓度≥0.1%时,必须向客户提供SDS说明该物质;
3、在物品中含有率>0.1%时,必须向客户或消费者说明该物质(至少说明物质名称)。

英文15种新的SVHC增加到候选清单:

 

SUBSTANCE NAME

EC
NUMBER

CAS
NUMBER

REASON FOR
PROPOSAL

POTENTIAL USES

1

Anthracene oil

292-602-7

90640-80-5

Persistent, bioaccumulative and toxic; Very persistent and very bioaccumulative; Carcinogen, category 21)

The substances are mainly used in the manufacture of other substances such as anthracene and carbon black. They may also be used as reducing agents in blast furnances, as components in bunker fuel, for impregnating, sealing and corrosion protection.

2

Anthracene oil, anthracene paste,distn. lights

295-278-5

91995-17-4

Persistent, bioaccumulative and toxic;Very persistent and very bioaccumulative;
Carcinogen, category 22); Mutagen, category 23)

3

Anthracene oil, anthracene paste,anthracene fraction

295-275-9

91995-15-2

Persistent,
bioaccumulative and toxic; Very persistent and very bioaccumulative; Carcinogen, category 22) Mutagen, category 23)

4

Anthracene oil, anthracene-low

292-604-8

90640-82-7

Persistent, bioaccumulative and toxic; Very persistent and very bioaccumulative; Carcinogen, category 22) Mutagen, category 23)

5

Anthracene oil, anthracene paste

292-603-2

90640-81-6

Persistent, bioaccumulative and toxic; Very persistent and very bioaccumulative; Carcinogen., category 22); Mutagen, category 23)

6

Pitch, coal tar, high temp.

266-028-2

65996-93-2

Persistent, bioaccumulative and toxic; Very persistent and very bioaccumulative; Carcinogen, category 2

Pitch, coal tar, high temp. is mainly used in the production of electrodes for industrial applications. Smaller volumes are dedicated to specific uses such as heavy duty corrosion protection, special purpose paving, manufacture of other substances and the production of clay targets.

7

Acrylamide

201-173-7

79-06-1

Carcinogen, category 2; Mutagen, category 2

Acrylamide is almost exclusively used for the synthesis of polyacrylamides, which are used in various applications, in particular in waste water treatment and paper processing. Minor uses of acrylamide comprise the preparation of polyacrylamide gels for research purposes and as grouting agents in civil engineering.

8

Aluminosilicate Refractory Ceramic Fibres Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.2 of Regulation (EC) No 1272/2008, and fulfil the two following conditions:
a) Al2O3 and SiO2 are present within the following concentration ranges:
• Al2O3: 43.5 – 47 % w/w,
and SiO2: 49.5 – 53.5 % w/w, or
• Al2O3: 45.5 – 50.5 %
w/w, and SiO2: 48.5 – 54 % w/w,
b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometers (μm).

-

-

Carcinogen, category 2

Refractory ceramic fibres are used for high-temperature insulation, almost exclusively in industrial applications (insulation of industrial furnaces and equipment, equipment for the automotive and aircraft/aerospace industry) and in fire protection (buildings and industrial process equipment).

9

Zirconia Aluminosilicate, Refractory Ceramic Fibres
Zirconia Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.2 of Regulation (EC) No 1272/2008, and fulfil the two following conditions:
a) Al2O3, SiO2 and ZrO2 are present within the following concentration ranges:
• Al2O3: 35 – 36 % w/w,
and
• SiO2: 47.5 – 50 % w/w,
and
• ZrO2: 15 - 17 % w/w,
b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometers (μm).

-

-

Carcinogen, category 2

Refractory ceramic fibres are used for high-temperature insulation, almost exclusively in industrial applications (insulation of industrial furnaces and equipment, equipment for the automotive and aircraft/aerospace industry) and in fire protection (buildings and industrial process equipment).

10

2,4-Dinitrotoluene

204-450-0

121-14-2

Carcinogen, category 2

2,4-dinitrotoluene is used in the production of toluene diisocyanate, which is used for the manufacture of flexible polyurethane foams. The substance is also used as gelatinizing-plasticizing agent for the manufacture of explosive mixtures (e.g. for airbags in cars).

11

Diisobutyl phthalate

201-553-2

84-69-5

Toxic for reproduction, category 2

Diisobutyl phthalate is used as plasticiser for nitrocellulose, cellulose ether, polyacrylate and polyacetate dispersions, and as a gelling aid in combination with other plasticisers, which are widely used for plastics, lacquers, adhesives, explosive material and nail polish.

12

Lead chromate

231-846-0

7758-97-6

Carcinogen, category 2; Toxic for reproduction, category 1

Lead chromate is used for manufacturing pigments and dyes, as a pigment or coating agent in industrial and maritime paint products or for embalming/restoring of art products. Further potential uses include as detergents and bleaches, photosensitive materials and for the manufacture of pyrotechnic powder.

13

Lead chromate molybdate sulphate red (C.I. Pigment Red 104)

235-759-9

12656-85-8

Carcinogen, category 2; Toxic for reproduction, category 1

Lead chromate molybdate sulphate red (C.I. Pigment Red 104) is used as a colouring, painting and coating agent in sectors such as the rubber, plastic and paints, coatings and varnishes industries. Applications comprise the production of agricultural equipment, vehicles and aircraft as well as road and airstrip painting.

14

Lead sulfochromate yellow (C.I.Pigment Yellow 34)

215-693-7

1344-37-2

Carcinogen, category 2; Toxic for reproduction, category 1

Lead sulfochromate yellow (C.I. Pigment Yellow 34) is used as a colouring, painting and coating agent in sectors such as the rubber, plastic and paints, coatings and varnishes industries. Applications comprise the production of agricultural equipment, vehicles and aircraft as well as road and airstrip painting. The substance is further used for camouflage or ammunition marking in the defence area.

15

tris(2-chloroethyl)phosphate

204-118-5

115-96-8

Toxic for reproduction, category 2

tris(2-chloroethyl)phosphate is mainly used as an additive plasticiser and viscosity regulator with flame-retarding properties for acrylic resins, polyurethane, polyvinyl chloride and other polymers. Other fields of application are adhesives, coatings, flame resistant paints and varnishes. The main industrial branches to use TCEP are the furniture, the textile and the building industry.

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